摘要
合成了４种新的单异丙基铝酸酯，分子量测定表明它们在苯中的缔合度为１．６～１．８，红外光谱推定存在铝配位数为５和６的二种双体，化合物的水解及热分解稳定性比短链的单异丙基铝酸酯稳定．比较讨论了这类化合物与相应的单异丙基二核铝酸酯在结构和性质上的异同．
Compounds of Al(OP)[O_2P(OR)_2]_2. Al(OP)[O_2P(R)(OR)]_2 and Al(OP)(O_2CR')_2(Where R=C_4H_9CH(C_2H_5)CH_2, R'=C_8H_17CH=CHC_7H_.4- or C_17H_35)weresynthesized by reactions of aluminium isopropoxide with relevant acids. Apparentmolecular weights obtained by vapor pressure studies showed that degrees ofpolymerization of the compounds in bezene were between 1.6 and 1.8.Their IR.spectra indicated that they existed in two forms of dimers. Their hydrolysis rates weremeasured by means of homogeneous phase hydrolysis. Themal stability in air obtainedby TGA showed that the compounds were quite stable.
出处
《中山大学学报（自然科学版）》
CAS
CSCD
1994年第3期54-59,共6页
Acta Scientiarum Naturalium Universitatis Sunyatseni
基金
中山大学自然科学基金资助项目
关键词
单异丙基
铝酸酯
合成
aluminium isopropoxide dibisalkylphosphate, acylates,infrared spectra,hydrolysis stability,themal stability
