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NMR Revealed Activated Alumina-Water Interaction

NMR Revealed Activated Alumina-Water Interaction
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摘要 Three different spin-lattice relaxation times ( T_1) of water were obtainedin activated alumina-water slurry system, which indicate that there exist three states of water;bound water, pore water and bulk water. The chemical shift (delta_H) decreasesas the amount of wateradded to the system increases due to the differences in contribution of these three states of waterin the samples. The delta_H value for adsorbed water decreases nearly linearly and T_1 increaseswith elevating temperature, whichresult from the decrease in the content of bound water by theincrease in thermal motion. Three different spin-lattice relaxation times ( T_1) of water were obtainedin activated alumina-water slurry system, which indicate that there exist three states of water;bound water, pore water and bulk water. The chemical shift (delta_H) decreasesas the amount of wateradded to the system increases due to the differences in contribution of these three states of waterin the samples. The delta_H value for adsorbed water decreases nearly linearly and T_1 increaseswith elevating temperature, whichresult from the decrease in the content of bound water by theincrease in thermal motion.
出处 《Wuhan University Journal of Natural Sciences》 EI CAS 2005年第3期572-576,共5页 武汉大学学报(自然科学英文版)
基金 SupportedbytheNationalNaturalScienceFoun dationofChina(20171035)
关键词 SLURRY WATER ~1H NMR ALUMINA relaxation time slurry water ~1H NMR alumina relaxation time
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