基团转移聚合反应中的有机硅引发剂

Silicone initiator in group transfer polymerization reaction

评述了近年来基团转移聚合反应中几种常用的有机硅引发剂(如单官能团引发剂、双官能团引发剂、其它乙烯酮硅烷缩醛引发剂、大分子引发剂及其它含硅引发剂)的研究进展,并展望了基团转移聚合反应在高分子合成中的重要作用及应用前景。

The recent development of several kinds of typical silicone initiators,i.e.monofunctional radical initiators,difunctional radical initiators,other silicon-containing initiators and macroinitiators,in the reaction of group transfer polymerization (GTP) were introduced,and the vital function and application prospect of group transfer polymerization in the synthesis of macromonomer were expected.