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5-磺酸钠水杨醛水溶性席夫碱及其金属配合物的合成与表征 被引量:3

Synthesis and characterization of water-solublesodium salicylaldimine-5-sulphonate Schiff baseand its metal complexes
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摘要 合成了双(5-磺酸钠水杨醛)丙酰二肼席夫碱及其Cu( ),Ni( ),Zn( ),Mn( ),Co( )的配合物,用元素分析、IR、摩尔电导和电子光谱对所得化合物进行了表征,对席夫碱配体还进行了1HNMR和MS表征,对所合成化合物的组成和结构进行了分析. <Abstrcat> The Schiff base of propanedioyl dihydrazide with sodium salicylaldimine-5-sulphonate and its Cu(Ⅱ),Ni(Ⅱ),Zn(Ⅱ),Mn(Ⅱ),Co(Ⅱ)complexes have been synthesized. These compounds have been characterized by elemental analysis,IR,molar conductivity and electronic absorption spectrum. The Schiff base ligand has been further characterized by ()~1H NMR and MS. The coordination composition and structure in these compounds are also analysed.
出处 《华中师范大学学报(自然科学版)》 CAS CSCD 2005年第2期208-211,共4页 Journal of Central China Normal University:Natural Sciences
基金 湖北省自然科学基金资助项目(98J048).
关键词 丙酰二肼 水溶性席夫碱 配合物 propanedioyl dihydrazide water-soluble Schiff base complex
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  • 1Doyle M P,Forbes D C. Recent advances in asymmetric catalytic metal carbene transformations[J]. Chem Rev,1998,98(2): 911~935.
  • 2Botsivali M,Evans D F,Missen P H. Studies on single oxygen in aqueous.part 2.Water-soluble square-planar nickel complexes as quenchers[J]. J Chem Soc Dalton Trans,1985(6): 1 147~1 149.
  • 3牛德仲,朱守荣,罗勤慧.双穴二氧四胺Cu(Ⅱ)和Ni(Ⅱ)配合物的合成和性质[J].无机化学学报,1994,10(1):1-5. 被引量:7
  • 4韦切尔 刘福官.乙二胺四乙酸在分析化学中的应用[M].北京:科学出版社,1965..
  • 5Geary W J. The use of conductivity measurements in organic solvents for the characterization of coordination compounds[J]. Coord Chem Rev,1971(7): 81 ~122.
  • 6Ledbetter J W. Infrared spectra of N-aryl imines of o-hy-droxybenz alde hyde between 2000 and 1500 cm-1[J]. J Phys Chem, 1997, 81: 54~59.
  • 7金满斗 朱文祥.配位化学研究方法[M].北京:科学出版社,1996..
  • 8Zolezzi S, Decinti A, Spodine E. Syntheses and characterization of copper(Ⅱ)complexes with Schiff-base ligands derived from ethlenediamine, diphenyle diamine and nitro, bromo and methoxy salicylaldehyde[J]. Polyhedron, 1999, 18: 897~904.
  • 9冯丽娟,谢静,胡学步,宋发辉,胡宗球,王成刚,祝心德.N,N'-二(5-溴亚水杨基)-2,6-吡啶二氨及其Cu(Ⅱ),Zn(Ⅱ)配合物的合成与表征[J].华中师范大学学报(自然科学版),2004,38(2):183-185. 被引量:5

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