期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

2,6-二甲酰基-4-甲基苯酚合成方法的改进 被引量：2

Studies on synthesis of 2,6-diformyl-4-methyl phenol
下载PDF
导出
摘要 对文献报道的以对甲笨酚为原料.三氟乙酸为溶剂,利用改进duff反应合成2,6-二甲酰基-4-甲基苯酚的反应过程进行了研究,改进了合成方法,缩短了反应时间,简化了操作步骤,提高了反应产率. The synthetic method of 2,6-diformyl-4-methylphenol in a modified Duff reaction is improved. Compared with the literature method, modification for the synthetic method leads to shortened reaction time, simplified operational processes and improved yield.
作者 徐强 宋仲容 陈凤鸣
机构地区 渝西学院化学与环境科学系
出处 《西南民族大学学报（自然科学版）》 CAS 2005年第4期525-526,共2页 Journal of Southwest Minzu University(Natural Science Edition)
基金 重庆市教委科学技术研究资助项目(031205).
关键词 2 6-二甲酰基-4-甲基苯酚 duff反应 合成改进 2,6-diformyl-4-methylphenol Duff reaction improved synthesis
分类号 O625.31 [理学—有机化学] O621.3 [理学—有机化学]
  • 相关文献

参考文献10

  • 1Duncan C A, Copeland E P, Kahw a I A, et al. Unusual formation and crystal structure of a new stable dinuclear vanadium(V) amino-imino-acetal[J]. J Chem Soc, Dalton Trans,1997: 917.
  • 2Wang Z, Martell A E, Motekaitis R J, et al. Dinuclear Fe(Ⅱ) macrocyclic complexes as catalysts for theoxidation of hydrocarbons by molecular oxygen[J]. Inorg Chem Acta, 2000: 300-302, 378.
  • 3Matthews K D, Kahwa I A, Williams D J. Preparation, structure, and luminescence of dinuclear lanthanide complexes of a novel imine-amine phenolate macrocycle[J]. Inorg Chem 1994, 33: 1382.
  • 4Grannas M J, Hoskins B F, Robson R. Synthesis and X-ray crystal structures of a calixarene-related, tetraamino, tetraphenolic,polynucleating macrocyclic ligand and its Zn^Ⅱ4 and Co^Ⅲ3 derivatives[J]. Inorg Chem 1994, 33: 1071.
  • 5Mohanta S, Nanda K K, Werner R, et al. Macrocyclic Cu^Ⅱ2, Cu^Ⅱ4, Ni^Ⅱ3, and Ni^Ⅱ4 complexes: magnetic properties of tetranuclear systems[J]. Inorg Chem, 1997, 36(21): 4656-4664.
  • 6Nanda K K, Venkatsubramanian K, Majumdar D, et al. Synthesis of a novel octaamino tetraphenol macrocyclic ligand and structure of a tetranuelear niekel(Ⅱ) comnlex[J]. Inorg Chem, 1994,33(8):1581-1582.
  • 7Gagne R R, Spiro C L, Smith T J, et al. The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization energy in a mixed-valent Cu^ⅠCu^Ⅱ complex[J]. J Am Chem Soc, 1981, 103: 4073-4081.
  • 8Synthetic Communications[J]. 2000. 30(9): 1555-1561.
  • 9Verani C N, Rentschler E, Weyhermllller T, et al. Exchange coupling in a bis(heterodinuclear) [Cu^ⅡNi^Ⅱ]2 and a linear heterotrinuclear complex Co^ⅢCu^ⅡNi^Ⅱ. Synthesis, structures and properties[J]. J Chem Soc, Dalton Trans, 2000:251-258.
  • 10Lindoy L F, Meehan G V, Svenstrup N. Mono-and diformylation of 4-substituted phenols: A new application of the Duffreaction[J].synthesis, 1998, (7): 1029-1032.

同被引文献8

  • 1马丙水,岳凡,段志明,郭新峰,王吉德.超声波辐射下合成2,6-二甲酰基-4-甲苯酚的研究[J].化学工程师,2005,19(2):4-6. 被引量：2
  • 2Leonard F Lindoy, George V Meehan, Niels Svenstrup. Mono- and diformylation of 4 -substituted phenols: a new application of the duff reaction [ J ], SYNTHESIS, 1998,7 : 1029 - 1032.
  • 3Pilkington N H, Robson R. Complexes of binucleating ligands( Ⅲ )novel complexes of a macrocyclic binucleating ligand [ J ]. Australian Journal of Chemistry, 1970, 23(11):2225 - 2236.
  • 4Ishenkumba A Kahwa, Susan Folkes, Davide J Williams, et al. The first crystal and molecular structure of lanthanide homodinuclear macrocyclic complexes showing metal - metal pair interactions [ J ]. J Chem Soe Chem Commum, 1989: 1531.
  • 5Kausik K Nanda, Ramprasad Das, Michel J Newlands, et al. Phenoxo - bridged dinickel (Ⅱ) complexes of a macrocyclic ligand : synthesis, stereochemical equilibria and structure[ J]. J Chem Soc Dalton Trans, 1992, 5: 897 - 901.
  • 6Sasankasekhar Mohanta, Kausik K Nanda, Ruldiger Werner, et al. Macrocyclic Cu2^Ⅱ, Cu4^Ⅱ, Ni3^Ⅱ, and Ni4^Ⅱ complexes: magnetic properties of tetranuclear systems [J].Inorg Chem, 1997, 36 : 4656 - 4664.
  • 7Kausik K Nanda, Krishnan Venkatsubramanian, Devashis Majumdar, et al. Synthesis of a novel octaamino tetraphenol macrocyclic ligand and structure of a tetranuclear nickel(Ⅱ) complex [J]. Inorg Chem, 1994, 33:1581 - 1582.
  • 8王军,李军舰,初红涛,苏立强,张有明,魏太保.微波辐射下2-苯并咪唑的绿色合成[J].化学研究与应用,2013,25(3):423-426. 被引量：8

引证文献2

二级引证文献1

西南民族大学学报（自然科学版）
2005年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部