摘要
The kinetics of internal oxidation of dilute Cu-Al alloys, containing 0.4475%-2.214%Al (mole fraction) was investigated over the temperature range of 1023-1273K and the depth of internal oxidation was measured by microscopy. Based on non-steady-state diffusion, a rate equation is derived to describe the kinetics of internal oxidation of plate: X=k-t-, where X is the oxidation depth, t is the oxidation time. For the internal oxidation of Cu-Al alloys employed in the synthesis of alumina dispersion strengthened copper, the permeability of oxygen in solid copper is obtained from the internal oxidation measurements. Investigation shows that the depth of the internal oxidation is a parabolic function of time, the typical shape of the front of internal oxidation is of planar morphology, and there is no evidence for preferential diffusion along grain boundaries.
The kinetics of internal oxidation of dilute Cu-Al alloys, containing 0.4475%-2.214%Al (mole fraction) was investigated over the temperature range of 1023-1273K and the depth of internal oxidation was measured by microscopy. Based on non-steady-state diffusion, a rate equation is derived to describe the kinetics of internal oxidation of plate: X=k-t-, where X is the oxidation depth, t is the oxidation time. For the internal oxidation of Cu-Al alloys employed in the synthesis of alumina dispersion strengthened copper, the permeability of oxygen in solid copper is obtained from the internal oxidation measurements. Investigation shows that the depth of the internal oxidation is a parabolic function of time, the typical shape of the front of internal oxidation is of planar morphology, and there is no evidence for preferential diffusion along grain boundaries.
出处
《中国有色金属学会会刊:英文版》
CSCD
2005年第3期589-593,共5页
Transactions of Nonferrous Metals Society of China
基金
Project(2002AA331112)supportedbyHitechandDevelopmentProgramofChina
Project(0122021300)supportedbytheNaturalScienceFoundationofHenanProvince,China
关键词
铜铝合金
非稳定态扩散
内部氧化
比例函数
Cu-Al alloys
non-steady-state diffusion
internal oxidation
rate equation