钯配合物偶氮型侧链液晶聚硅氧烷的晶体结构

THE CRYSTAL STRUCTURE OF Pd-COORDINATING AZO-TYPE SIDE CHAIN LIQUID CRYSTALLINE POLYSILOXANE

本文以ＸＲＤ研究了一种偶氮类液晶聚硅氧烷铅配合物的晶体结构（Ｐｄ－ＡＺＬＣＰ）．结果表明，Ｐｄ－ＡＺＬＣＰ的晶胞属单斜晶系．经过计算机处理求出了晶胞参数为ａ＝１６．１８，ｂ＝４．０５，ｃ＝１０．９６，ａ＝９０．０°，β＝１１２．４°，γ＝９０．０°。根据晶胞参数和侧链基团的大小，提出了晶体中分子排布的结构模型．

The crystal structure of Pd-AZCP was studied by XRD. The result shows that theunit cell of Pd-AZLCP is monoclinic one.The cell constants were given through the computer treat-ment. A schematic model of molecule arrangement in crystal state was given according to the cellconstant and the size of side chain group.