4－（4′－烷氧基－4－酚氧基－1－丁氧基苯氧碳基）苯并－15－冠－5的合成

SYNTHESIS OF THE 4-(4'-ALKOXYL-4-PHENOLOXY-1-BUTOXYL PHENOXYCA RBONYL)BENZO-15-CROWN-5

本文由４－氯甲酰基苯并－１５－冠－５和４，４＇－二羟基－α，ω－二苯氧丁烷反应，合成了一系列４－取代的苯并－１５－冠－５．合成的化合物Ⅰ、Ⅱ和Ⅵ的组成和结构经ＩＲ、ＮＭＲ和元素分析证实．由化合物Ⅱ和Ⅳ的表征可见，由化合物Ⅱ和Ⅵ的熔点随分子中末端基碳原子数目的增加，逐渐降低．

A series of the 4-(4’-alkoxyl-4-phenoloxy-1-butoxylphenoxycarbonyl)benzo-15-crown-5 have been sy nthesized. The structures,of these compounds are characterized by IR,NMR spectroscopy and elemental analysis.It can be seen that the inelting points decrease when the cdrbon numbers of the end group increase.