摘要
Two modes of heterogeneous photoisomerization of trans-vitamin D3 to cis-vitamin D3 are described. The occurrence of isomerization on the substrate bounded to the polymeric support gives us the possibility in succession synthesis of 1α-hydroxyvitamin D3. The polymer-bound anthracene can sensitize isomerization of trans-vitamin D3 to cis-vitamin D3 efficiently and ease the separation process.
基金
This work was supported by the Major State Basic Research Development Program,Grant No.G2000078100
the National Natural Science Foundation of China,No.20172059 and Chinese Academy of Sciences.
