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Synthesis and Crystal Structure of Poly{diaqua[N-(2-hydroxybenzyl)- D,L- aspartate]cadmium(II)}

Synthesis and Crystal Structure of Poly{diaqua[N-(2-hydroxybenzyl)- D,L- aspartate]cadmium(II)}
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摘要 The title compound, [Cd(C11H11NO5)(H2O)2]n, crystallizes in orthorhombic, space group Pbca with a = 8.521(3), b = 10.154(3), c = 28.804(8) ?, V = 2492.2(13) ?3, Z = 8, C11H15NO7Cd, Mr = 385.64, Dc = 2.056 g/cm3, F(000) = 1536, μ(MoKα) = 1.786 mm-1, the final R = 0.0424 and wR = 0.0859 for 2026 observed reflections with I > 2σ(I). It has a one-dimensional zig-zag chain structure along the a axis driven by Cd–O coordination bonds. Three kinds of hydrogen bonds connect the chains along the b axis into a two-dimensional structure. The title compound, [Cd(C11H11NO5)(H2O)2]n, crystallizes in orthorhombic, space group Pbca with a = 8.521(3), b = 10.154(3), c = 28.804(8) ?, V = 2492.2(13) ?3, Z = 8, C11H15NO7Cd, Mr = 385.64, Dc = 2.056 g/cm3, F(000) = 1536, μ(MoKα) = 1.786 mm-1, the final R = 0.0424 and wR = 0.0859 for 2026 observed reflections with I > 2σ(I). It has a one-dimensional zig-zag chain structure along the a axis driven by Cd–O coordination bonds. Three kinds of hydrogen bonds connect the chains along the b axis into a two-dimensional structure.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第7期759-762,736,共5页 结构化学(英文)
基金 This work was supported by the National Natural Science Foundation of China (No.20231020)
关键词 crystal structure metal coordination hydrogen bonding crystal structure, metal coordination, hydrogen bonding
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  • 1Janiak, C. Dalton Trans. 2003, 2781-2804.
  • 2Seidel, S. R.; Stang, P. J. Acc. Chem. Res. 2002, 35,972-983.
  • 3Moulton, B.; Zaworotko, M. J. Chem. Rev. 2001, 101, 1629-1658.
  • 4Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34, 319-330.
  • 5Slang, E J. Chem. Eur. J. 1998, 4, 19-27.
  • 6Zhang, J. J.; Sheng, T. L.; Hu, S. M.; Xia, S. Q.; Leibeling, G.; Meyer, E; Fu, Z. Y.; Chen, L.; Fu, R. B.; Wu, X. T.Chem. Fur. J. 2004, 10, 3963-3969.
  • 7Weng, J. B.; Hong, M. C.; Cao, R.; Shi, Q.; Chan, A. S. C. Chinese J. Struct. Chem.2003, 22, 195-199.
  • 8Kim, H. J.; Moon, D.; Lab, M. S.; Hong, J. I. Angew. Chem. Int. Ed. 2002, 41, 3174-3177.
  • 9Hong, M. C.; Zhao, Y. J.; Su, W. P.; Cao, R.; Fujita, M.; Zhou, Z. Y.; Chan, A. S. C. J. Am. Chem. Soc. 2000, 122, 4819-4820.
  • 10Zhang, X. M.; Wu, H. S.; Chen, X. M. Chinese J. Struct. Chem. 2004, 23,407-412.

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