摘要
为了构造一个具有有效电荷转移的给-受体体系,通过1,3-偶极加成反应,由5-[2-′(4″-醛基苯氧丙氧苯基)]-10,15,20-三苯基卟啉(H2P-CHO)、肌氨酸和C60首次合成了一种新的以共价键相连的富勒烯-卟啉配体(H2P-C60),同时用该配体制备了其锌配合物(ZnP-C60),并用红外光谱、元素分析、电子光谱、核磁共振氢谱和质谱等方法进行了表征.
In order to construct a donor-acceptor system with efficient electron transfer, a novel covalently linked fullerene-porphyrin ligand(H_2P-C_-{60-}) was synthesized by 1,3-dipolar cycloaddition reaction of C_-{60-}, sarcosine and H_2P-CHO, and it′s zinc derivative was prepared by metalation of H_2P-C_-{60-} and zinc acetate. The two new fullerene-porphyrin compounds were characterized by means of elemental analysis, IR, electronic spectra, ESI-MS and -{-}~1H NMR.They are also predicted to have good optical and electrical properties.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2005年第7期1202-1205,M003,共5页
Chemical Journal of Chinese Universities
基金
福建省自然科学基金(批准号:E0410001)
厦门大学自选课题基金(批准号:0040-Y07008)资助
关键词
富勒烯
富勒烯吡咯烷
卟啉
金属卟啉
Fullerene
Fulleropyrrolidine
Porphyrin
Metal Porphyrin
