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波聚合制备淀粉接枝丙烯酸钠-丙烯酰胺高吸水性树脂 被引量:19

Preparation of Starch-g-Sodium Acrylate/Acrylamide Superabsorbent via Frontal Polymerization
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摘要 A new method for the preparation of a starch-graft-sodium acrylate-co-acrylamide superabsorbent using a thermal propagating front was described. The frontal polymerization(FP) is a simple mode of polymerization in which a localized zone of reaction propagates in an unstirred medium, converting monomer to polymer. Because no additional heat is needed after the initial application, the process has potential advantages over traditional polymerization methods: lower processing costs, faster reaction rate, and less energy input. These advantages make the frontal polymerization a potential viable option in polymer synthesis. Scanning electron microscope picture shows that porous superabsorbent can be synthesized by FP. The superabsorbent swelled fast with high water and salt solution absorbency. A new method for the preparation of a starch-graft-sodium acrylate-co-acrylamide superabsorbent using a thermal propagating front was described. The frontal polymerization(FP) is a simple mode of polymerization in which a localized zone of reaction propagates in an unstirred medium, converting monomer to polymer. Because no additional heat is needed after the initial application, the process has potential advantages over traditional polymerization methods: lower processing costs, faster reaction rate, and less energy input. These advantages make the frontal polymerization a potential viable option in polymer synthesis. Scanning electron microscope picture shows that porous superabsorbent can be synthesized by FP. The superabsorbent swelled fast with high water and salt solution absorbency.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2005年第7期1363-1365,M009,共4页 Chemical Journal of Chinese Universities
基金 国家自然科学基金(批准号:50372008)资助.
关键词 波聚合 淀粉接枝 高吸水树脂 Frontal polymerization Starch graft Superabsorbent
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