(2,2-双二茂铁基丙烷)-6,6′-二甲酸的合成与表征

Synthesis and characterization of(2,2-bisferrocenylpropane)-6,6'-bi(methanic acid)

用2,2-双二茂铁基丙烷与邻氯苯甲酰氯在AlCl3催化下合成了6,6′-二(邻氯苯甲酰基)双二茂铁基丙烷,然后在叔丁醇钾的存在下解离成相应的(2,2-双二茂铁基丙烷)-6,6′-二甲酸。利用元素分析、红外光谱和核磁共振氢谱对合成的化合物进行了表征。

In this paper,6,6-bi(o-chloride-benzoyl)-bisferrocenyl propane was synthesized by the reaction of 2,2-bisferrocenylpropane and o-chloro-benzoylchloride,then,the corresponding carboxylic acid was synthesized in the presence of C_4H_9OK.All the compounds were new,and their structures were confirmed by elemental analysis,IR,(()~1HNMR).