分光光度法测定络合物稳定常数的数据处理问题

Data Processing for Spectrophotometric Determination of the Complex Stability Constant

本文论述关于分光光度法测定络合物稳定常数中的两个问题,一个是关于消光值的校正方法问题,一个是关于络合稳定常数K的计算问题,即采用迭代法解方程K=求得x的值。

Two problems about Spectrophotometric determination of the complex stability constant were discussed in this aricle.The one is about the rectifying method of extinction .The other one is about the calculating method of the complex stability constant (k)— solving the equation K=x(a_1-x)(b_1-nx)~n=x(a_2-x)(b_2-nx)~n by the alternate algorithm.