苄基氯水解动力学的研究

KINETIC STUDY ON HYDROLYSIS OF BENZYL CHLORIDE

编制ＦＯＲＴＲＡＮ程序，在ＭＢＥ－１６００２计算机上处理了苄基氯碱性水解的实验数据．提出反应机理是含有可逆步骤的ＳＮ＿１和ＳＮ＿２同时存在的平行反应。求得反应的活化能分别是３７．４ＫＪｍｏｌ￣（－１）和９５．６ＫＪｍｏｌ￣（－１）。

In the solution of 50% alcohol-water the kinetic data of basic hydrofysis of benzylchloride were treatmented on computer MBE-16002.The mechanism of the reaction is suggested tobe parallal reactions consisted reversible stepe. The activition energy of the processes SN_1 and SN_2are 37. 4KJ/mol,95.6KJ/mol respectively.