在二甲亚砜溶剂中氯化钼氧卟啉和超氧自由基反应动力学研究Ⅰ反应中间物和反应动力学

Kinetic Studies of Reaction of Oxomolybdenum Tetraphonylporphrin Complex MoO(TPP) Cl with in the Presence of DMSO I Intermediates and Kinetics

本文应用紫外－可见吸收光谱研究了高浓度二甲亚砜存在条件下，ＭｏＯ（ＴＰＰ）Ｃｌ与超氧自由基的反应。通过研究确定了一系列反应中间物和反应产物，本文还报导了有关反应动力学数据和结果。

The kinetics of the reaction of MoO(TPP)Cl with superoxide anion radical in high concentration of DMSO has been studied , and a series of in-termediates were investigated. The kinetics results were discussed and the kinetic data raported.