摘要
研究表明,在四苯氧基酞菁锰配合物中,锰能够以Mn(Ⅱ),Mn(Ⅲ),Mn(Ⅳ)三种稳定氧化态存在,各氧化态之间的转变可以通过化学氧化还原、光氧化还原以及电解氧化还原来实现。
Our investigation shows that, in the complex of TPhOPcMn, manganese can have three stable oxidation states-Mn(Ⅱ), Mn(Ⅲ) and Mn(Ⅳ), the shift of which can be realized through chemical, photochemical and electrochemical reaction.
关键词
锰络合物
苯氧基
酞花菁
光化学
Phenoxy group
Phthalocyanine(P)
Manganese complex
Oxidation-reduction reaction
Photochemical reaction
Electrochemical reaction
Absorption spectrometry
