摘要
尝试使用９种多核金属磺化酞菁催化环己烯的环氧化反应，结果表明它们对环己烯在氧气作氧源的环氧化反应有催化作用。通过正交试验，发现以多核磺化酞菁镍（Ⅱ）、多核磺化酞菁钴（Ⅱ）和多核磺化酞菁铁（Ⅲ）的催化活性为佳。
Nine multi-nuclear metal sulfo-phthalocyanines had been used as catalysts for epoxidation of cyclohexene. The experiment results showed that they have catalytic activity for epoxidation of cyclohexene with molecular oxygen and multi-nuclear ferric sulfo-phthalocyanine, multi-nuclear cobaltous sulfo-phthalocyanine and multi-nuclear nickelous sulfo-phthalocyanine have better catalytic activity for epoxidation of cyclohexene
出处
《东北师大学报（自然科学版）》
CAS
CSCD
1995年第1期79-82,共4页
Journal of Northeast Normal University(Natural Science Edition)
关键词
多核金属
磺化酞菁催化
环己烯
环氧化
配合物
catalyzed by multi-nuclear metal sulfo-phthalo cyanines
expoxidation
cyclohexene molecular oxygen
orthogonal test
