含多硫基和吡啶配体的四核铜簇合物合成与表征

Composition and Characterization of Four-nucleon Copper Cluster Containing Polysulfide Group and Pyridine Ligands

采用铜粉、硫粉、硫化钾及３－甲基吡啶在常湿、常温下直接合成了标题化合物。它是橙红色晶体，不溶于水反常规有机溶剂。通过元素及热分析、红外光谱、电化学性质以及Ｘ射线结晶学等特征．

The title compound has been obtained by the reaction of copper powder with sulfur powder, potassium sulfide and 3-methylpyridine at ambient temperature and normal atmosphere. The colour of the crystal is orange-red and the crystal is insoluble in normal organic solvent. The structure is characterized by elemental analysis, infraved spectra,thermal analysis, electro-chemistry and X-ray crystallograph.