邻羟基苄基氨乙酸及其络合物的研究（Ⅷ）──CO（Ⅱ）络合物与H_2O_2的氧化还原反应动力学及机理

Studies on N-o-hydroxybenzylglycine and its complexes(Ⅷ)──Mechanism and kinetics of redox reaction between cobalt(Ⅱ)complex and hydrogen peroxide

用分光光度法研究了Ｃｏ（Ⅱ）－ＨＢＧ络合物与Ｈ２Ｏ２的氧化还原反应动力学及反应机理，求得动力学参数及第一步反应的热力学常数ΔＨ≠、ΔＳ≠．作者认为，此氧化还原反应不可能按内层电子转移的机理进行，而是经过外层电子转移机理进行的．

Mechanism and kinetics of redox reaction between cobalt(Ⅱ) complex of N-o- hydroxybenzylglycine(HBG) and H2O2 have been investigated spectrophotometrically. The kinetic parameter and the thermodymic quantities, ΔH≠ and ΔS,of the first reaction have been obtained.Autors propose that the electron transfer prefer to occur through outer sphere mechanism.