1，3－取代方酸衍生物的光谱研究及二聚体、簇集体的形成

SPECTROSCOPIC STUDY OF 1,3-SUBSTITUTED SQUARIC ACID DERIVATIVES AND ITS DIMER,AGGREGATE FORMATION

本文合成了１，３－取代方酸衍生物：１，３－双［４－二甲胺苯基］－２，４二羟基环丁二烯氢氧双内盐（ＤＭＣＳ），１，３－双［４－双十六烷胺苯基］－２，４二羟基环丁二烯氢氧双内盐（ＤＨＣＳ）。研究了ＤＭＣＳ和ＤＨＣＳ在不同溶剂中的光物理行为，估算了ＤＭＣＳ、ＤＨＣＳ的基态与激发态之间偶极矩差值。在ＣＴＡＢ胶束中，除ＤＭＣＳ单体分子外，ＤＭＣＳ形成了二聚体。在二氧六环－水体系中，研究了ＤＨＣＳ的簇集行为，并测定了ＤＨＣＳ的临界簇集组成（Ｃ＿ψ）及临界簇集浓度（Ｃ＿Ａ）

The compounds 1,3-bis(4-dimethyaminopheny1)-2,4-dihydroxy-dihydroxide cy-clobutenediylium bis(inner salt)[DMCS]and 1,3-bis(4-dihexadecylaminopheny1)-2,4-di-hydroxy-dihydroxide cyclobutenediylium bis(inner salt)[DHCS]were synthesized.The photophysical behaviors of DMCS and DHCS in different solvents were studied and their differences of dipole moment between ground state and excited state were calculated.Dimer ofDMCS in CTAB and aggregate of DHCS in dioxane-water were investigated and criticalaggegation composition(C_Ψ)and critical aggregation concentration(C_A)of DHCS weremeasured.