摘要
合成了三(3-苯基-4-苯甲酰基异唑酮-5)-乙醇-水合铕的配合物。有关鉴定和元素分析结果表明:该配合物的分子式为[Eu(PBI)3(C2H5OH)(H2O)]·H2O,其中3-苯基-4-苯甲酰基异唑酮-5简记为HPBI,是一种新型高酸度的β-双酮。用X射线单晶衍射法测定了[Eu(PBI)3(C2H5OH)(H2O)]·H2O的晶体结构,结果表明,该晶体属单斜晶系,P21/a空间群,晶胞参数:a=1.5586(9)nm,b=2.1297(7)nm,c=1.604(1)nm,β=117.97(5)°,V=4.703(9)nm3,Z=4.中心离子铕为八配位,其配位多面体为畸变的双帽三棱柱。配位的8个氧原子分别来自3个PBI配体中的6个氧、1个溶剂化乙醇分子中的氧和1个水分子中的氧,Eu—O配位键平均键长0.2391(4)nm。晶体结构中还存在1个未配位的水分子。该水分子、配位水分子、乙醇分子与配体PBI中的N原子之间均存在强的氢键作用。同一PBI基团内配位氧之间的平均距离为0.2808nm。
The[Eu(PBI)3(C2H5OH)(H2O)]·H2O was systhesized by reacting Eu2O3 with highly acidic β-diketone 3-phenyl-4-benzoyl-5-isoxazolone(HPBI) in C2H5OH under heating.The X-ray single crystal structure analysis shows that the crystal is monoclinic with space group P2 1/a and the unit cell parameters are as follows:a=1.5586(9) nm,b=2.1297(7) nm,c=1.604(1) nm,β=117.97(5)°,V=4.703(9) nm3,Z=4.The central ion Eu3+ is eight coordinated by six oxygen atoms from three β-diketone,one from water and one from C2H5OH molecule.The coordination polyhedron takes bicapped triangular prism arrangement.The Eu-O average bond length is 0.2391(4) nm.The average distance of O-Owithin a β-diketone is 0.2808 nm which is larger than those for other β-diketones.
出处
《高等学校化学学报》
CSCD
北大核心
1995年第2期172-175,共4页
Chemical Journal of Chinese Universities
基金
国家科学技术委员会攀登计划资助