摘要
荧光法研究含长链烷基聚丙烯酰胺的疏水微区结构邱星屏,张雪蓉,丁马太(厦门大学化学系,厦门,361005)关键词萘酚,聚丙烯酰胺,疏水微区聚丙烯酰胺作为增粘剂和絮凝剂,已用于石油开采、水处理等领域[1].在聚丙烯酰胺链上引进少量疏水侧基,可显著地改变其...
In this paper,1-naphthol has been used as a fluorescence probe to investigate the hydrophobic microdomain structure formed by hydrophobically modified polyacrylamide in aqueous solution.It was found that 1-naphthol molecules are soluble in spherical SDS micelles but insoluble in the hydrophobic microdomains of AM-co-HDMAM.The solubility difference indicated that,owing to the steric hindrance of polymer backbone,the hydrophobic microdomains of AM-co-HDMAM should have a less integrated micellar structure than SDS micelles.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1995年第8期1321-1323,共3页
Chemical Journal of Chinese Universities
基金
福建省自然科学基金