摘要
制得5种金和铂的冠醚类配合物,用元素分析、红外和紫外光谱、摩尔电导和~1H核磁共振谱等方法研究了配合物的组成及其有关性质。
Five solid complexes of gold (Ⅲ) or platinum (Ⅳ) with crown ethers have been preparedfirstly. These complexes have been characterized by elemental analysis, IR and UV spectra,molar conductances and ~1H NMR measurements. The complexes were found to have followingconstitution: [K (B15C5)_2]AuCl_4, [Na(B15C5)_2 ]PtCl_6, (K18C6)]AuCl_4, [K(DB15C5)]AuCl_4and [NH_4(DB24C8)]AuCl_4, where B=benzo, DB=dibenzo.
出处
《应用化学》
CAS
CSCD
北大核心
1989年第5期31-34,共4页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金