微乳状液体系中草酸酯发光反应特性的研究

A Research on Chemiluminenscence Characteristics of the Diaryl Oxalates in Microemulsion

本文讨论了不溶于水的芳基草酸酯如4—硝基酚草酸酯(4—NPO)在壬基酚聚氧乙烯(10)醚(TX—10)+醇复配体系与邻苯二甲酸二丁酯(DBP)形成的微乳状液系统中的发光反应特性,并就其胶团基本模型作了定性数学分析,得到与实验曲线相一致的结果:即扩散过程是微乳状液中芳基草酸酯化学发光反应的控制步骤。

Chemiluminenscenee Characteristics of insoluble diaryl oxaiates in water (such as 4 ?NPO) in microemulsion system which is made of TX-10+alcohol. Solution and DBP are discussed in this paper. A mathematical qualitative analysis for the basic micell model is made. The result which comforms with experimental curve is obtained. That means the diffusion process is the determining step of chemiluminenscence reaction of diaryl oxaiates with H2O2in microemalsion.