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胜利油田原油碱水体系的界面电性 被引量:1

ELECTROKINETIC STUDY OF INTERFACE BETWEEN CRUDE OIL AND ALKALINE AQUEOUS SYSTEM
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摘要 测定了胜利原油在 Na_4SiO_4、NaOH 水溶液中形成的乳状液的界面电性,并考察了无机盐的影响。与大港原油相比,胜利原油在碱水中具有稍高的电泳淌度,其极大值所对应的碱浓度也略低。原油酸值对界面电性有影响。在我们的研究中,酸值较低的原油一般在碱水中具有较低的电泳淌度。在溶液中加入二价阳离子使电泳淌度降低。钙离子对电泳淌度的影响大于镁离子。 The interfacial electrokinetic behaviour (electrophonetic mobility) of emulsions consis- ting of some Shengli crude oils and aqueous solutions of Na_4SiO_4 and NaOH and the influ- ence of inorganic salts on this property are studied in this paper.In comparision with one of Dagang crude oils Shengli crude oils give higher electrophoretic mobilily with lower alka- line concentration at maximum mobility.Interfacial electrokinetic hehaviour is affected by acidity of the crude oil.In general cases the lower the acid value of a crude oil the lower electrophonetic mobility it gives in aqueous emulsions.Divalent cations existed in aqueous solutions decrease electrophonetic mobilities at interfaces of crude oil/aqueous alkaline solu- tion emulsions,while Ca^(++) is more influencing than Mg^(++) does.
出处 《油田化学》 CAS CSCD 北大核心 1989年第1期76-79,共4页 Oilfield Chemistry
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