摘要
用新型萃取剂均二苯基-16-冠-5-氧代乙酸研究了Sr ̄(2+)和Y ̄(3+)的萃取。结果表明,在适当pH条件下,Y ̄(3+)可以定量地被萃取,而Sr ̄(2+)几乎全部留在水相中。利用斜率法确定了均二苯基-16-冠-5-氧代乙酸与Y ̄(3+)的配合物组成比为1:2。建立了从 ̄(90)Sr中萃取无载体高纯放射性 ̄(90)Y的方法。
The Solvent extraction of and is studied with a new type extractant sym-dibenzo-16- crown- 5-oxyacetic acid (HL) in chloroform. is quantitatively extracted at pH6.5,whereasthe extraction of Sr ̄(2+)is negligible. Separation of from can be achieved by solvent extrac-tion with HL. The mechanism of extraction of Y ̄(3+) is discussed.
出处
《核化学与放射化学》
CAS
CSCD
北大核心
1995年第2期105-109,共5页
Journal of Nuclear and Radiochemistry
关键词
苯基
氧代乙酸
萃取
钇90
锶90
冠醚
Sym-dibenzo-16- crown-5-oxyacetic acid Solvent extraction