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用均二苯基-16-冠-5-氧代乙酸从^(90)Sr-^(90)Y中萃取~(90 被引量:1

A STUDY OF SOLVENT EXTRACTION OF FROM WITH SYM-DIBENZO-16-CROWN-5-OXYACETICACID
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摘要 用新型萃取剂均二苯基-16-冠-5-氧代乙酸研究了Sr ̄(2+)和Y ̄(3+)的萃取。结果表明,在适当pH条件下,Y ̄(3+)可以定量地被萃取,而Sr ̄(2+)几乎全部留在水相中。利用斜率法确定了均二苯基-16-冠-5-氧代乙酸与Y ̄(3+)的配合物组成比为1:2。建立了从 ̄(90)Sr中萃取无载体高纯放射性 ̄(90)Y的方法。 The Solvent extraction of and is studied with a new type extractant sym-dibenzo-16- crown- 5-oxyacetic acid (HL) in chloroform. is quantitatively extracted at pH6.5,whereasthe extraction of Sr ̄(2+)is negligible. Separation of from can be achieved by solvent extrac-tion with HL. The mechanism of extraction of Y ̄(3+) is discussed.
作者 杜鸿善 Wai,CM
出处 《核化学与放射化学》 CAS CSCD 北大核心 1995年第2期105-109,共5页 Journal of Nuclear and Radiochemistry
关键词 苯基 氧代乙酸 萃取 钇90 锶90 冠醚 Sym-dibenzo-16- crown-5-oxyacetic acid Solvent extraction
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参考文献2

  • 1杜鸿善,Nucl Instr Meth Phys Res A,1986年,251卷,254页
  • 2杜鸿善,化学学报,1981年,6卷,512页

同被引文献34

  • 1金小海,于海滨,张锦明,张培新,林琼芳.^(90)Sr-^(90)Y发生器的研制[J].同位素,1990,3(3):161-169. 被引量:8
  • 2程作用,李茂良,曹志坚.DTPA作为^(90)Sr/^(90)Y发生器淋洗剂的研究[J].核动力工程,1993,14(6):543-546. 被引量:3
  • 3何龙海,翁锡,杨大助,宋崇立.冠醚萃取法从高放废液中去除锶Ⅲ.二环己基18冠6-辛醇-[2]对锶的萃取[J].核化学与放射化学,1994,16(1):18-22. 被引量:17
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