摘要
利用诱导效应指数建立了一个用以计算合硫含氮有机物标准生成热的简单方法,利用此法计算了一些常见含硫含氮有机物的标准生成热,32个可比较值的平均偏差为2.6kJ·mol-1。
A simple formula for calculating the standard formative heat of organic compounds containing nitrogen or sulfur using the inductive effect index is established in this paper. The standard formative heats of some general organic compounds containing nitrogen or sulfur are calculated, the available average deviations of thirty-two compounds are 2. 6 kJ.mol-1.
关键词
标准生成热
含硫
含氮
有机物
诱导效应
standard formative heat
inductive effect index
organic compounds containing nitrogen or sulfur