讨论碰撞理论中的校正因子P

Discussion on the Correct Factor P in the Theory of Collision

本文用气体分子动力学推导了碰撞理论中的气相双分子反应速度公式,它自然包括了校正因子P。从引用的几个例子的计算结果看还比较合理,但在一般的《物理化学》书中,校正因子P却必须靠经验决定。

This article lead a reactive speed equation of gaseous phase double molecules in the theory of collision with the dynamics of gas molecules. It naturally includes correct factor P.It is still reasonable from the calculated results of the examples quoted. But the correct factor P must be determine dby experiment in general《Phsical Chgemistry》books