N－1－烷基硫甲基苯并三氮唑的合成

The Synthesis of N 1 alkylthiomethylbenzotriazoles

通过烷基硫醇钠与１－氯甲基苯并三氮唑的亲核取代反应，高产率地合成了两个长链烷基硫甲基苯并三氮唑新化合物和一个由工业级原料合成的长链烷基硫甲基苯并三氮唑产物．所得的新型化合物通过了元素分析．￣１ＨＮＭＲ、￣１３ＣＮＭ－Ｒ、ＩＲ和ＭＳ等图谱分析．根据有关文献报道，这类新型化合物不仅是潜在的合成长链不对称硫醚的中间体，而且是潜在的优良无灰多功能润滑油添加剂．

Two novel long-chain alkylthiomethyl-benzotriazoles and a industrial product are synthesized conviniently in high yield using the reaction of sodium alkyl mer-captide and 1-chloromethylbenzotriazole in iso-propanol at room temperature.The structures of these novel compounds were identified by the elemental analy-sis,1HNMR,13CNMR,IR and MS analysis.According.to literatures,these novel compounds are potentially mutifunctional lubricating oil additives and synthetic intermediate for asymmetric thio ethers.