固相配位化学反应研究 LⅨ.反应截面移动法研究氢氧化铜与α-alaH的固相反应

Studies on the Solid State Reaction of Coordination Compounds LⅨ. Investigation of Solid State Reaction of Cu(OH)_2 and α-alaH by Intersection Face Moving Method

本文提出用反应截面法研究氢氧化铜和α-alaH的室温固相反应,讨论了反应温度及表面状态等影响截面移动的因素,对表面反应速度的决定因素进行了讨论并计算了反应活化能.

Intersection face moving methed is designed to study the solid state reaction of Cu(OH)2 and α3-alaH at room temperature. The influence of reaction temperature, molar ratio and surface condition are investigated. In this system, the interface chemical reaction is the rate determined step of the apparant reaction, and the activation energy is calculated as 39.8kJ·mol-1.