摘要
用含时微扰理论两态近似法处理分子间振动能传递,导出了电场中分子间共振V—V传能的跃迁几率、态—态反应截面与反应速度常数表达式。
Using the two state approximation of the time dependent porturbation theory,the formu-las of the transition probability,the state state reaction cross section and rasection rate for resor-nant vibration vibration energy transfer between molecules in a electric field have been derived.
出处
《化学研究与应用》
CAS
CSCD
1995年第1期23-26,共4页
Chemical Research and Application
关键词
双原子分子
微扰理论
V-V传能
跃迁几率
电场
time dependent perturbation,two state approximation,vibration vibration energy transfer