高氯酸钬（Ⅲ）和双（苯基亚砜）丙烷、双（苯基亚砜）丁烷配合物的光谱性质

SPECTRAL PROPERTIES OF HO￣3+ COMPLEXES OF BIS(PHENYLSULFINYL)PROPANE AND BIS(PHENYLSULFINYL)BUTANE

测量了高氯酸钦（Ⅲ）和双（苯基亚砜）丙烷、双（苯基亚砜）丁烷配合物的溶液（甲醇－氯仿，二甲基甲酰胺）的电子光谱，计算了ｆ－ｆ跃迁的振子强度和强度参数，并讨论了“超灵敏”跃迁的强度和强度多数与配体性质的关系和溶剂的影响。

The Ho￣3+ complexes of bis(phenylsulfinyl)propane and bis(phenylsulfinyl)butane in thesolution of CH_3OH- CHCl3_ and DMF have been spectrophotome trically investigated,The The observedspectra in visible region have been analysed useillator strengths and porameters being calculated.The oscillator strengths of hypersensitive transition and perameter are correlated with the properties ofligand and are influenced by solvent.