摘要
以邻苯基苯酚(OPP)、三氯化磷和1,4-对苯醌等为原料,一锅法合成了含磷化合物2-(6H-二苯并<c,e><1,2>-5-氧杂-6-膦酰杂-6-苯基-1,4-对苯二酚(DOPO-HQ)阻燃剂,收率达86%,通过红外光谱、核磁共振和DSC等分析测试手段对产物结构进行了表征。
A phosphorus - containing monomer, 2 - （ 6 - oxido - 6H - dibenz 〈 c, e〉〈 1, 2 〉 oxa phosphorin - 6 -yl） -1, 4- dihydroxy phenylene （DOPO- HQ）, was synthesized using o-phenyl phenol, phosphorus trichloride and 1,4 - benzoquinone as raw materials, and the yield of the DOPO - HQ is 86%. The final product was characterized by FTIR, ^1H - NMR and DSC.
出处
《合成技术及应用》
2005年第2期19-21,共3页
Synthetic Technology & Application
基金
国家自然科学基金资助项目(50203008)
