摘要
Three complexes Cu（ppca）2（H2O）2（NO3）2 （1）, Cu2（μ-OH）2（ppca）2（H2O）4）·（ClO4）2 （2） and Cu2（μ-CH3COO）4（ppca）2（3） have been synthesized by the reaction of copper（Ⅱ） salts with N-phenyl-4-pyridinecarboxamide （ppca） and characterized. For anions, in complex 1, NO3^- coordinated with copper（Ⅱ）, in complex 2 perchlorate anion did not take part in coordination, the copper（Ⅱ） cations were connected by μ-OH to form a dinuclear unit, and complex 3 had a dimeric copper（Ⅱ） carboxylate paddle-wheel core. Noncovalent interactions linked these complexes to form supramolecular networks. Different coordinating modes of anions controlled modes of intennolecular interactions, which resulted in different final structures.
Three complexes Cu（ppca）2（H2O）2（NO3）2 （1）, Cu2（μ-OH）2（ppca）2（H2O）4）·（ClO4）2 （2） and Cu2（μ-CH3COO）4（ppca）2（3） have been synthesized by the reaction of copper（Ⅱ） salts with N-phenyl-4-pyridinecarboxamide （ppca） and characterized. For anions, in complex 1, NO3^- coordinated with copper（Ⅱ）, in complex 2 perchlorate anion did not take part in coordination, the copper（Ⅱ） cations were connected by μ-OH to form a dinuclear unit, and complex 3 had a dimeric copper（Ⅱ） carboxylate paddle-wheel core. Noncovalent interactions linked these complexes to form supramolecular networks. Different coordinating modes of anions controlled modes of intennolecular interactions, which resulted in different final structures.
基金
Project supported by the Natural Science Foundation of Education Bureau of Liaoning Province, China.
