摘要
A new flexible double betaine L (L = 1,4-bis(pyridinio-4-carboxylato-N-methyl)benzene, C20H16N2O4) and its cadmium(Ⅱ) complex [Cd(H2O)aL(NO3)]NO3.H2O 1 were synthesized. Complex 1 was obtained by self-assembly reaction of [Cd(NO3)2]-4H2O and L in hot water,and its crystal structure was determined by single-crystal X-ray diffraction analysis. Crystallographic data for complex 1: C20H24CdN4O14.H2O, Mr = 674.85, monoclinic, space group P21/c, a =13.7854(3), b = 14.2820(3), c = 14.9188(4) ,A°, β = 116.418(1)°, V = 2630.5(1)A°^3, Z = 4, Dc= 1.704g/cm^3,/J(MoKα) = 0.911 mm^-1, F(000) = 1368, the final R = 0.0315 and wR = 0.0768 for 3637 observed reflections with I 〉 2σ(I). In complex 1, L acts as a monodentate ligand to link a Cd(Ⅱ) ion in a novel coordination mode of double betaines. The mononuclear [Cd(H2O)aL(NO3)] units are connected through intermolecular hydrogen bonds and π-π stacking reactions to generate a 3D network.
A new flexible double betaine L (L = 1,4-bis(pyridinio-4-carboxylato-N-methyl)benzene, C20H16N2O4) and its cadmium(Ⅱ) complex [Cd(H2O)aL(NO3)]NO3.H2O 1 were synthesized. Complex 1 was obtained by self-assembly reaction of [Cd(NO3)2]-4H2O and L in hot water,and its crystal structure was determined by single-crystal X-ray diffraction analysis. Crystallographic data for complex 1: C20H24CdN4O14.H2O, Mr = 674.85, monoclinic, space group P21/c, a =13.7854(3), b = 14.2820(3), c = 14.9188(4) ,A°, β = 116.418(1)°, V = 2630.5(1)A°^3, Z = 4, Dc= 1.704g/cm^3,/J(MoKα) = 0.911 mm^-1, F(000) = 1368, the final R = 0.0315 and wR = 0.0768 for 3637 observed reflections with I 〉 2σ(I). In complex 1, L acts as a monodentate ligand to link a Cd(Ⅱ) ion in a novel coordination mode of double betaines. The mononuclear [Cd(H2O)aL(NO3)] units are connected through intermolecular hydrogen bonds and π-π stacking reactions to generate a 3D network.
基金
This work was supported by the NSF for Distinguished Young Scientist of China (20425104) and the NSF of Fujian Province (2005I017, A0420002)