摘要
First total synthesis of triprenylquinone and hydroquinones, three naturally occurringcompound 1, 2 and (±) 3, have been achieved from readily available 2-bromo-5-methyl-1,4-dimethoxybenzene 4 and geranyl bromide. The triprenylquinone and hydroquinones precursor were readily prepared with use of a Julia reaction.
First total synthesis of triprenylquinone and hydroquinones, three naturally occurringcompound 1, 2 and (±) 3, have been achieved from readily available 2-bromo-5-methyl-1,4-dimethoxybenzene 4 and geranyl bromide. The triprenylquinone and hydroquinones precursor were readily prepared with use of a Julia reaction.
基金
This research work was financially supported by the National Natural Science Foundation of China(Grant No.20272020).