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甲醇在Pt-Sn/GC上的电催化氧化 被引量:2

Electrocatalytic oxidation of methanol at glassy carbon electrode with platinum and tin (Pt-Sn/GC)
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摘要 The preparation for Pt and Pt-Sn modified Glassy Carbon Electrode by Cyclic voltammerty method was studied in methanol solution.The results indicated that the catalysis effect of Pt-Sn/GC on the onidation of methanol was best when it made by 4∶1 of H2PtCl6 and SnCl4 solution.And the catalysis activation was also changed with the Pt-Sn quantity and the temperature.The reaction mechanism and parameter of kinetics were detected by different scan rates. The preparation for Pt and Pt-Sn modified Glassy Carbon Electrode by Cyclic voltammerty method was studied in methanol solution. The results indicated that the catalysis effect of Pt-Sn/GC on the onidation of methanol was best when it made by 4:1 of H2PtCl6 and SnCl4 solution. And the catalysis activation was also changed with the Pt-Sn quantity and the temperature. The reaction mechanism and parameter of kinetics were detected by different scan rates.
出处 《化学研究与应用》 CAS CSCD 北大核心 2005年第4期520-522,共3页 Chemical Research and Application
关键词 循环伏安法 Pt-Sn/GC Pt/GC 甲醇 电催化氧化 Cyclic voltammerty method Pt-Sn/GC Pt/GC methanol electrocatalytic oxidation
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