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有序介孔材料形成机理的研究进展 被引量:2

Recent Advances in Research on the Formation Mechanisms of Organized Mesoporous Materials
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摘要 简要介绍了自1992年以来有序介孔材料形成机理的研究进展,重点介绍了几个重要的反应机理模型,如液晶模板机理模型、棒状自组装机理模型、层状折叠机理模型、电荷密度匹配机理模型、协同作用机理模型、真液晶模板机理模型、氢键-π-π-堆积协同作用机理模型等。并对有序介孔材料形成机理的研究提出了自己的观点和见解。 This paper reviews the advances in research on the formation mechanisms of ordered mesoporous materials since 1992, and casts light on a few models, such as liquid crystal template mechanism, silicate rod assembling mechanism, silicate layer puckering mechanism, charge density matching mechanism, cooperative formation mechanism, true liquid crystal template mechanism, hydrogen bond-co-π-π-stack mechanism. Our opinions on the research that should be launched especially in the future are also elucidated.
出处 《化学与生物工程》 CAS 2005年第8期1-3,共3页 Chemistry & Bioengineering
基金 国家自然科学基金资助项目(50272048)
关键词 介孔材料 液晶模板 自组装 mesoporous materials liquid crystal templates self-assemble
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  • 1Chiola V, Ritsko J E, Vander C D. Process for producing low-bulk density silica[P]. USP3 356 725,1971.
  • 2Kresge C T, Leonowicz M E, Roth W J, et al. Ordered mesoporous molecular sieves synthesized by a liquid-crystal templated mechanism[J]. Nature, 1992, 359: 710-712.
  • 3Chen C Y, Li H X, Davis M E. Studies on mesoporous materials. I. synthesis and characterization of MCM-41[J]. Micropor Mater, 1993, 2: 17-26.
  • 4Steel A, Carr S W, Anderson M W. 14NNMR study of surfactant mesophases in the synthesis of mesoporous silicates[J]. Chem Commun, 1994:1571-1572.
  • 5Monnier A, Schüth F, Huo Q, et al. Cooperative formation of inorganic-organic interfaces in the synthesis of silicate mesostructures[J]. Science, 1993, 261: 1299-1303.
  • 6Firouzi A, Kumar D, Bull L M, et al. Cooperative organization of inorganic-surfactant and biomimetic assemblies[J]. Science, 1995, 267: 1138-1143.
  • 7Huo Q, Margolese D I, Ulrike C, et al. Generalized synthesis of periodic surfactant/inorganic composite materials[J]. Nature, 1994, 368: 317-321.
  • 8Attard G S, Glyde J C, G ltner C G. Liquid-crystalline phases as templates for the synthesis of mesoporous silica[J]. Nature, 1995, 378:366-368.
  • 9Zhou Y, Schattka J H, Antonietti M. Room-temperature ionic liquid as template to monolithic mesoporous silica with wormlike pores via a sol-gel nanocasting technique[J]. Nano Lett, 2004, 4: 477-481.
  • 10Zana R, Frasch J, Soulard M, et al. Fluorescence probing investigations of the mechanism of formation of organized mesoporous silica[J]. Langmuir, 1999, 15:2603-2606.

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