水滑石类材料碱性催化性能的应用研究

Study on application of hydrotalcite-like materials' catalytic performances in basic reactions

以绿色化学为基础,综述了类水滑石及其以类水滑石为前驱体衍生的复合氧化物作为一类优异的固体碱催化剂应用于醇醛缩合、克诺文诺盖尔(Knoevenagel)缩合、麦克尔(M ichael)加成以及酯交换等反应的最新研究进展。预测了水滑石类材料由于具有特殊的结构和性质必将在环境友好的催化工业体系中扮演越来越重要的角色。

Based on “ Green” chemistry , this paper mainly reviewed the latest research advance of the hydrotalcite-like materials and their derived composite oxides as an excellent solid base catalyst used in aldol condensation, Knoevenagel condensation, Michael addition, transesterification reactions and so on.It was forecasted that the hydrotalcite-like material would play more and more important role in the environmental catalysis industry, because of their special structure and properties.