摘要
苯并三唑—1—乙酰肼与苯甲酰氯在无水四氢呋喃溶液中反应,得到新配体N—苯甲酰基一N’—苯并三唑乙酰肼(双酰肼)。用此配体与二价金属(Cu,Ni,Cd,Zn,Co,Pb)醋酸盐在乙醇溶液中回流1h,合成了六个新配合物,产率在65％～78％之间。经元素分析,红外光谱,核磁共振氢谱和热重分析,确定了它们的结构为四配位聚合态结构。
A new diacylhydrazide has been synthesized by the reaction of benzotriazol-1-acetylhydrazine with benzoyl chloride in absolute tetrahydrofuran. Its divalent metal complexes have been prepared by refluxing the ligand and the hydrated metal acetate in ethanol for Ih; yield 65-78%. These compounds have been characterized by elemental analyses, IR, 1HNMR and TGA.
出处
《兰州医学院学报》
1995年第4期210-212,共3页
Journal of Lanzhou Medical College
基金
甘肃省自然科学基金
关键词
双酰肼
苯并三唑
配合物
Diacylhydrazide
Benzotriazole
Complex
