摘要
据V2+离子在刚玉中的电子顺磁共振谱，我们研究了它在刚玉中的位置。研究结果表明：V2+离子并不占据准确的Al3+离子位置，而是沿着C轴向氧八面体中心位移大约0.004nm。位移方向和本文提出的刚玉中的杂质离子位移模型是一致的。
The lattice site of V2+ ion in corundum has been studied in terms of its electron paramagneticresonance parameters. lt is found that the V2+ ion does not occupy the exact site of the replacedAl3+ion,instead is displaced about 0. 004nm along the c-axis and is close to the center of oxygen oc-tahedron. The displacement direction is consistent with the impurity displacement model suggestedin this paper.
出处
《矿物学报》
CAS
CSCD
北大核心
1995年第3期324-327,共4页
Acta Mineralogica Sinica
基金
国家教委优秀年轻教师基金
关键词
刚玉
钒离子
电子顺磁共振
corundum
V^(2+) ion
electron paramagnetic resonance
