摘要
二苯基吡啶基膦是个优良的双齿配体。用它制得了铁配合物和含铁－铑的双核配合物。铁－铑双核配合物作为甲醇羰基化制乙酸和乙酸甲酯的催化剂，转化率达１００％，选择性为９９％。对铁配合物和铁－铑双核配合物进行了红外、核磁和穆斯堡尔谱测定。
Pheny1-Pyronylphosphine is a good dinod ligand. This ligand can react with iron compound to form complex. The Fe-Rh binuclear complex containing Pheny1-Pyronylphosphine was prepared. This Fe-Rh complex is a good catalyst for carbonylation of methanol to form aceticacid and methyl acetate. The conversion of methanol is 100% and selectivity is 99%. Phsicochemical studies including the infrared, nuclear magnetic resonance absorption and Mossboaur spectrum were performed on the Fe-Rh complex.
出处
《南开大学学报（自然科学版）》
CAS
CSCD
1995年第1期21-27,共7页
Acta Scientiarum Naturalium Universitatis Nankaiensis
基金
国家自然科学基金
关键词
配合物
配体
二苯基吡啶
合成
铁
complex catalyst
ligand
phenyl-pyronylphosphine
