摘要
本试验利用傅里叶变换红外光谱仪考察了2,4-二氨基-1,5-二甲硫基(DADMT)和N,N-二(2-羟乙基)苯胺(lsonol)分别与聚酯型预聚物和了羟型预聚物固化反应过程,求出相应体系的反应动力学常数和表观活化能。并对扩散控制阶段的反应过程进行了分析和讨论。
The reactions of DADMT with and isonol with prepolymer of polyester-TDI and hyolroxy-terminated polybutadiene--TDI were respectively investigated by Fourier transform infrared. The correspoding kinetics constants and activation energies were obtained. Then kinetics constsnt in diffussion--controlled stage were analysized and discussed.
出处
《青岛化工学院学报(自然科学版)》
1995年第3期241-246,251,共7页
Journal of Qingdao Institute of Chemical Technology(Natural Science Edition)
关键词
聚氨酯
固化剂
动力学
固化
树脂
polyester
firming agent
kinetics
solidification
Fourier transform infrared