摘要
利用连续和脉冲反应技术,考察了添加少量氧对丙烷在Ga/HZSM-5上催化芳构化的影响。试验结果表明,氧的存在对丙烷转化为芳烃BTX不利。通过进一步条件试验,对氧的作用进行了分析讨论,认为这与催化剂中活性组份镓的存在直接相关。
The effect of O_2 on propane aromatization over Ga/H2SM-5 is tested by continuous/pul-sative-reactor techniques. Addition of O_2 in the feeding gas strongly inhibits the conversion ofpropane to aromatic hydrocarbons. The role of O_2 is discussed in detail,and it is proposed that theoxygen effect is caused by the gallium active species in the catalyst.
出处
《石油化工》
CAS
CSCD
北大核心
1995年第7期456-459,共4页
Petrochemical Technology
关键词
沸石
芳构化
丙烷
氧
催化异构化
Ga/HZSM-5 zeolite,aromatization,propane,oxygen