摘要
利用固定床反应器,研究了铜系催化剂对甲醇脱氢合成甲酸甲酯的催化性能。试验结果表明,Cu-ZnO-ZrO_2/SiO_2,催化剂具有较高的活性,在适宜的反应条件下,甲酸甲酯的产率在20%以上,用XRD测试对催化剂表面物相进行了表征分析。
The dehydrogenation of metbanol to methyl formate in a fixed-bed reactor with Cu catalystscontaining Zn and Zr supported on SiO_2 was studied. The catalyst Cu-ZnO-ZrO_2 /SiO_2 showedhigher activity and selectivity. The yield of methyl formate is over 20%under suitable condi-tions. The Catalysts were characterized by X-ray diffraction.
出处
《石油化工》
CAS
CSCD
北大核心
1995年第9期610-613,618,共5页
Petrochemical Technology