摘要
K-Fe-MnO/Si-2催化剂具有较佳的CO2加氢合成低碳烯烃性能,并随碱金属钾助剂的添加而明显改善;其CO2加氢反应具有(1)CO2+H2CO+H2O和(2)CO+(m/2n+1)H21/nCnHm+H2O两步反应机理;应用该反应机理,解释了CO2/H2比、反应温度、反应压力、反应气空速等对K-Fe-MnO/Si-2催化剂CO2加氢反应性能的影响;探讨了催化剂中K2O助剂的作用。
Desirable performance of K-Fe-MnO/Si-2catalyst in CO2 hydrogenation for production of light olefins can be achieved and greatly improved with adding K2O as a promoter. A two-step mechanism is suggested for CO2 hydrogenation to form hydrocarbons, by which the effect of variation in reaction conditions such as temperature, pressure and gas space velocity as well as CO2/H2 ratio on the behavior of the K-Fe-MnO/Si-2 catalyst is explained reasonably. The role of K2O promoter is also discussed.
出处
《天然气化工—C1化学与化工》
CAS
CSCD
北大核心
1995年第5期6-10,共5页
Natural Gas Chemical Industry
基金
大连化物所青年基金
关键词
二氧化碳
低碳烯烃
催化剂分子筛
铁
加氢
carbon dioxide, light olefins,Fe-MnO catalyst, Silicalite-2 zeolite