摘要
作者研究了DBC-偶氮与稀土元素的显色反应.1.7mol/L盐酸介质中,该试剂与铈组稀土元素形成稳定的蓝紫色配合物.以双峰双波长(测定波长630nm,参比波长520nm)测定时,灵敏度高,表观摩尔吸光系数为1.49×105.稀土含量在0~20.0μg/25.00mL范围内呈良好的线性关系,标准偏差小于0.002%.
The color reaction of cerium group Rare earth with DBC-Arsenazo has been studied,it is shown that the blue-violet complex is formed in the 1. 7 mol/L HCL medium. The determination wavelength is 630 nm,the reference wavelength is 520urn. The appearent molar absorptivity is 1.49×105.Beer'law is obey6d in the range of 0-20. 0μg/25mL for Rare earth. The relative standard deviation is<0. 002%.