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某些结构受阻氧鎓盐的吸收和荧光 被引量:2

Absorption and Fluorescence of some Pyrylium Salts with Hindered Structure
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摘要 A series of pyrylium compounds with different structures have been synthesized. The photophysical behavior of these compounds has also been measured. Results show that the structures of compounds and the polarities of solvents make great effects on the photophysical behaviors of compounds, especially when the structures of compounds are hindered. It indicats that the intramolecular rotation relaxation of compounds in excited state in closely related to the fluorescence quantum yields of compounds. A series of pyrylium compounds with different structures have been synthesized. The photophysical behavior of these compounds has also been measured. Results show that the structures of compounds and the polarities of solvents make great effects on the photophysical behaviors of compounds, especially when the structures of compounds are hindered. It indicats that the intramolecular rotation relaxation of compounds in excited state in closely related to the fluorescence quantum yields of compounds.
作者 陈懿 吴世康
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1995年第10期916-920,共5页 Acta Physico-Chimica Sinica
基金 国家自然科学基金
关键词 氧Wong盐 吸收 荧光 分子 电荷转移 Pyrylium salt, Absorption, Fluorescence, Intramolecular charge transfer
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  • 1D. Basting,F. P. Sch?fer,B. Steyer. New laser dyes[J] 1974,Applied Physics(1):81~88

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