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杂多酸在活性炭表面含氧基团上的化学键合作用 被引量:16

Chemical Bonding between Heteropoly Acid and Oxygen-containing Groups on the Surface of Activated Carbon
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摘要 In order to define the force of heteropoly acids on adsorbed activated carbon surface, IR spectra of 12-silicotungstic acid (SiW12) and 12-tungstophosphoric acid(PW12) adsorbed on activated carbon and in oxygen-containing orgainc compound solutions were studied. Based on the IR spectra and UV characteristics of the heteropolyacids in vaxious chemical conditions, the chemical bonding between heteropoly acid andoxygen-containing groups on the surface of activated carbon was suggested. In order to define the force of heteropoly acids on adsorbed activated carbon surface, IR spectra of 12-silicotungstic acid (SiW12) and 12-tungstophosphoric acid(PW12) adsorbed on activated carbon and in oxygen-containing orgainc compound solutions were studied. Based on the IR spectra and UV characteristics of the heteropolyacids in vaxious chemical conditions, the chemical bonding between heteropoly acid andoxygen-containing groups on the surface of activated carbon was suggested.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1995年第12期1105-1109,共5页 Acta Physico-Chimica Sinica
关键词 活性炭 杂多酸 吸附 化学键合 催化剂 Activated carbon, Heteropoly acid, Adsorption
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参考文献4

  • 1王新平,叶兴凯,吴越.杂多酸的固载化研究(Ⅱ)[J].物理化学学报,1994,10(4):303-307. 被引量:13
  • 2王新平,催化学报,1993年,增刊,172页
  • 3梁娟,催化剂新材料,1990年
  • 4赖卡特 C,有机化学中的溶剂效应,1987年

二级参考文献1

  • 1高尚愚,炭素,1984年,119卷,207页

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